HKUST Library Institutional Repository Banner

HKUST Institutional Repository >
Chemistry >
CHEM Conference Papers >

Please use this identifier to cite or link to this item: http://hdl.handle.net/1783.1/1121
Title: Ruthenium complexes of bis(diphenylthiophosphosphoryl)amide
Authors: Zheng, Hegen
Chim, Joyce L. C.
Chan, Joe
Wong, Wing-Tak
Leung, Wa-Hung
Keywords: Synthesis
Crystal structures
Ruthenium complexes
Bis(diphenylthiophosphosphoryl)amide
Issue Date: 1997
Citation: Proceedings of Symposium on Frontiers of Chemistry - in conjunction with the Second Conference for Worldwide Chinese Young Chemists (CWCYC-2), p. 409-410
Abstract: Transition metal-sulfur complexes have attracted much attention because of their resemblance to the active sites of redox metalloenzymes and their potential applications to homogeneous catalysis. The crystal structure of nitrogenase reveals that the active center of the enzyme contains a Fe-Mo-S cluster. However, the mechanism by which the N-N triple bond of nitrogen is activated in the Fe-Mo-S active center remains unclear. Owing to the periodic relationship between Fe and Ru, one may expect that the more subsitutionally inert Ru-sulfur complexes may serve as structural and functional models for Fe-S enzymes. Additionally there is an increasing interest in Ru-S complexes because they are found to be better hydrodesulfurization catalysts than the commercial Mo-S systems. We here describe the synthesis and crystal structures of some ruthenium complexes of bis(diphenylthiophosphosphoryl)amide (L).
URI: http://hdl.handle.net/1783.1/1121
Appears in Collections:CHEM Conference Papers

Files in This Item:

File Description SizeFormat
cwcyc07.pdf218KbAdobe PDFView/Open

All items in this Repository are protected by copyright, with all rights reserved.