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Please use this identifier to cite or link to this item: http://hdl.handle.net/1783.1/1132
Title: Biomimetic catalysts by nanoscale confined metalloporphyrins in zeolite
Authors: Zhan, Bi-Zeng
Li, Xiao-Yuan
Keywords: Zeolite
Metalloporphyrin
Issue Date: 1997
Citation: Proceedings of Symposium on Frontiers of Chemistry - in conjunction with the Second Conference for Worldwide Chinese Young Chemists (CWCYC-2), p. 662-663
Abstract: Cytochrome P-450 enzymes catalyze the oxidation of various unactivated alkanes and alkenes with distinguished reaction specificity, substrate selectivity, and high efficiency under mild conditions. Encapsulation of synthetic MP and MPc in the nanometer-sized supercages of zeolite, namely "ship-in-a-bottle", is a promising approach, in which microporous zeolites play the similar role as does an apoprotein for a P-450 enzyme. We report here a novel and efficient "build-a-bottle-around-the-ship" method for the nanoinclusion of metalloporphyrin in the supercage of faujasite-Y.
URI: http://hdl.handle.net/1783.1/1132
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